(2405.15650) Tuning structural modulation and magnetic properties in metal-organic coordination polymers (CH$_3$NH$_3$)Co$_x$Ni$_{1-x}$(HCOO)$_3$

View a PDF of the paper titled Tuning structural modulation and magnetic properties in metal-organic coordination polymers (CH$_3$NH$_3$)Co$_x$Ni$_{1-x}$(HCOO)$_3$, by Madeleine Geers and 2 other authors

View PDF

Abstract:Three solid solutions of (CH$_3$NH$_3$)Co$_x$Ni$_{1-x}$(HCOO)$_3$, with $x$ = 0.25 (1), 0.50 (2) and 0.75 (3), were synthesized and their nuclear structures and magnetic properties were characterized using single crystal neutron diffraction and magnetization measurements. At room temperature, all three compounds crystallize in the Pnma orthorhombic space group, akin to the cobalt and nickel end series members. Upon cooling, each compound undergoes distinct series of structural transitions to modulated structures. Compound 1 exhibits a phase transition to a modulated structure analogous to the pure nickel compound, while compound 3 maintains the behavior observed in the pure cobalt compound, although in both cases the temperatures at which the phase transitions occur differ slightly from the pure phases. Monochromatic neutron diffraction measurements showed that the structural evolution of 2 diverges from that of either parent compound, with the competing hydrogen bond interactions which drive the modulation throughout the series producing a unique sequence of phases. It involves two modulated phases below 96(3) K and 59(3) K, with different q vectors, similar to the pure cobalt compound (with modulated phases below 128 K and 96 K), however it maintains the modulated phase below magnetic order (at 22.5(7) K), resembling the pure nickel compound (which presents magnetic order below 34 K), resulting in an improper modulated magnetic structure. Despite these large scale structural changes, magnetometry data reveal that the bulk magnetic properties of these solid solutions form a linear continuum between the end members. Notably, doping of the metal site in these solid solutions allows for tuning of bulk magnetic properties, including magnetic ordering temperature, transition temperatures, and the nature of nuclear phase transitions, through adjustment of metal ratios.